In the aluminum high pressure die casting (HPDC) process, the molten aluminum alloy is injected into reusable steel dies at high speeds (gate speeds of between 25 and 45 m/sec) and high pressures of 70 to 100 MPa or higher. To try to prevent the liquid metal from soldering (sticking) to the steel die, lubricants (parting agents) are sprayed into the die surface prior to each shot, but some level of soldering often still occurs. In addition, the rapid cooling of the die surface by the lubricant spray can promote heat checking, thereby dramatically shortening the life of the die. During aluminum HPDC, core pins located near the gate experience extreme conditions, such as higher temperatures and greater soldering and abrasion/erosion due to interactions with the flowing liquid metal. One possible solution for minimizing soldering and to address the extreme conditions adjacent to the gate is the application of hard coatings to these more vulnerable regions of the die. However, the decision-making process for selecting appropriate coatings for application to dies is often still very subjective. Several researchers have attempted to use laboratory tests for evaluating the effectiveness of various coating materials, but these laboratory tests typically lack the high gate speeds and pressures that are inherent to the die casting process. While more complex and realistic tests have been performed using laboratory-based or production die casting machines, only a limited number of die coatings have been examined, mostly produced by the PVD process. In the study reported here, a commercial die used to produce large automotive die castings was examined, as it incorporated two core pins located directly in front of the gate. A range of PVD, PACVD and diffusion coatings were applied to the core pins, and both qualitative and quantitative measurements were used to identify the amount of aluminum soldered to each coated pin. Characterization of the soldered interfaces was performed to understand coating failure, and to indicate best die coatings for aluminum HPDC applications.

Polymeric materials are used in a wide range of applications including packaging, bottle caps, furniture, window frames, as well as automotive parts and high-end components. The manufacturing process often includes injection molding or extrusion processes. To achieve long lifetime, performance, and stability in high volume manufacturing processes, coatings are applied on the parts of the tooling that are in contact with the polymer melt. Increasing requirement for high-strength light-weight materials, for example driven by E-mobility, promote the use of polymers with high percentage of glass-fiber or carbon-fiber reinforcement. The use of biopolymers is also increasing. Consequently, the conditions for tools and components are becoming harsher and typically involve a combination of abrasive wear, corrosion, and plastic adhesion. To allow performance enhancements in the contemporary plastics processing industry, we describe the development of a coating solution based on CrON. The selection of coating materials, tuning of coating architecture, and coating properties will be discussed and correlated with application requirements and performance.

Preferred for Session G3