ICMCTF2011 Session G4/E4: Coatings for Machining Advanced Materials and Advanced Manufacturing Methods

Wednesday, May 4, 2011 8:00 AM in Room California

Wednesday Morning

Time Period WeM Sessions | Abstract Timeline | Topic G Sessions | Time Periods | Topics | ICMCTF2011 Schedule

Start Invited? Item
8:00 AM G4/E4-1 Nanocomposite (Ti,Cr,Al,Si)N Coatings for Hard Machining of PM High Speed Steel
Kirsten Bobzin, Fritz Klocke (RWTH Aachen University, Germany); Kristian Arntz (Fraunhofer-Institut für Produktionstechnologie IPT, Germany); Nazlim Bagcivan (RWTH Aachen University, Germany); Martin Stolorz (Fraunhofer-Institut für Produktionstechnologie IPT, Germany); Mara Ewering, Lore Stalpers (RWTH Aachen University, Germany)

PM (powder-metallurgical) high speed steels are increasingly employed as tool materials for cold work applications due to their high abrasion resistance and toughness. Nevertheless, the machining of these materials is very challenging due to vanadium and iron carbides which lead to high abrasive wear on the cutting edges as well as the high toughness of these materials which leads to adhesive wear.

To meet these challenges nitride nanocomposite coatings seem to be promising. In the present work (Ti,Cr,Al,Si)N coatings were deposited on cemented carbides via MSIP (Magnetron Sputter Ion Plating) and investigated using XRD, SEM and scratch test. Different working points within the nitrogen hysteresis were chosen to optimize the coating’s morphology and mechanical properties.

The developed coating was deposited on ballnose end mills and tested in milling of S790PM, 62HRC (1.3345, M3 class 2) in comparison to two different commercial coatings: (Ti,Al)N deposited via MSIP and (Ti,Cr,Al,Si)N deposited via Arc Ion Plating. As tool life criterion a flank wear width of 100 µm was chosen. It could be shown that, depending on the cutting parameters, the tool life is increased by 20 - 30% by the new developed coating.

8:20 AM G4/E4-2 Substrate Surface Etching Effects on Machining Performance of Diamond-Coated Cutting Tools
Raymond Thompson, Dustin Nolen (Vista Engineering); Feng Qin, Kevin Chou (University of Alabama)

For carbide tools, the cobalt binder phase is a very good solvent of carbon, and thus, in diamond deposition process, diamond nucleates on these substrates through a non-diamond layer. The weak graphite layer at the interface results in poor adhesion, which is the main technical challenge to enhance machining performance of diamond-coated tools. Substrate surface modifications are the key solutions to grow highly adherent diamond on carbide tools. Chemical etching is a widely applied method. Though low-cost, the control of material removal process is lack of precision and uniformity. Thus, variations in the etching effect and consequent tool performance may be significant.

In this study, both conventional etching (CE) and electrolytic etching (EE) methods were tested to remove substrate surface cobalt. The substrates used were 6 wt.% cobalt fine-grain tungsten carbides of square-shape inserts . After etching, diamond films were produced by a high-power microwave plasma-assisted CVD process, with a thickness of about 20 µ m. A computer numerical control lathe was used to perform machining experiments to evaluate the wear behavior of differently etched tools. Workpieces were round bars made of A359/SiC-20p composite. Machining parameters used consisted of two levels of cutting speeds and feeds. During machining testing, the cutting inserts were periodically inspected by optical microscopy to measure flank wear-land. Worn tools after testing were also examined by scanning electron microscopy.

The preliminary results show that (1) the coated EC tools have better delamination resistance under indentation loads, (2) The coated CE tools have rougher surfaces, (3) the EC tools have less flank wear, though same wear patterns, and a longer tool life compared to CE tools. The results indicate that electrolytic etching can be an effective alternative to enhance interface adhesion, and thus, tool wear resistance. In addition, effects on machining performance are dependent upon machining conditions.

8:40 AM G4/F4-4 Influence of Edge Micro-Geometry and Coating Design on the Drilling of Titanium Alloys with Carbide Drills
Antony Pilkington, Steve Dowey, Jimmy Toton (RMIT University and Defence Materials Technology Centre, Australia); Darren Griffett (Cuttertec Pty, Australia); Oscar Smith (Sutton Tools Pty, Australia); Edward Doyle (RMIT University and Defence Materials Technology Centre, Australia)

The increasing use of Titanium alloys in advanced civil and military aerospace manufacturing has created a demand for continuous improvement in the performance and reliability of round shank tooling. Evolutionary advances in tool design are achieved by optimising the substrate, macro and micro geometry, surface finish and through PVD coating with the latest generation high performance ceramic materials.

In this work Ti6Al4V titanium alloy plate was drilled with 6.5mm diameter carbide drills with conventional soluble oil coolant. Machining parameters were varied between 25-80m/min and feed rates of 0.1-0.25mm/rev. The drill performance was quantified by metal removal rate and compared to an un-coated tool. A force dynamometer was used to measure torque and thrust forces. Hole quality metrics were investigated using an infinite focus microscope (IFM) to measure hole surface roughness and burr height on entry and exit. Different edge treatments of 3-30 microns were applied to the tooling. The as-ground sharp drill lips were modified by a conventional chamfer, which was ground during tool manufacture and a blended radius was applied by nylon abrasive filament brushing (NAF) with a 500 grit SiC peripheral brush. The effect of PVD coating the drills was also investigated, both in the as deposited condition and after post-polishing by aluminium oxide NAF brushing. The torque and thrust data from the drilling tests was compared to a model derived by treating the drill cutting lip as an assembly of concentric single point tools. This practical model used data generated from orthogonal cutting tests using single edge carbide tooling with systematically varied rake, clearance and edge micro-geometries. IFM measurements of the edge micro-geometry were made to determine the detail of the shape factors created by the edge treatments. The effects of the edge offsets a,b and radii R on the cutting forces were investigated during the turning experiments. The results contribute to improved drill design for the optimisation of high performance hole-making in titanium components.

9:00 AM G4/E4-5 Coating and Tool Wear in Composite Machining
Johan Bohlmark (Sandvik Tooling Stockholm SE, Sweden); Eleanor Merson, Wan Tsin Goh (Sandvik Tooling Sheffield, UK)
Composite materials are compositions of two or more materials with significantly different physical properties with their respective properties kept intact on a microscopical level in the finished structure. The most commonly used composites are Carbon Fibre Reinforced Plastics (CFRP) and Glass Fibre Reinforced Materials (GFRP). These materials can offer high strength in combination with low weight, and are therefore popular structural materials in, for example, modern aircrafts. Machining operations of these materials can differ significantly from traditional metal machining, and are usually very challenging for cutting tools. Composite materials are abrasive, and obtaining long tool life is always a challenge in composites drilling. The abrasiveness of these materials is thought to be affected by their fibre volume, cure temperature, glass transition temperature, fibres types, cutting conditions used, etc. Research into various coatings and polycrystalline diamond (PCD) has been carried out and tests on different materials to study the wear behavior and the wear resistance of these coatings on tool wear have been performed. Although uncoated drills are commonly used in industries, test results reveal that coated WC/Co and PCD insert drills offer better tool life. Different types of tools are subjected to different wear mechanisms. Tools coated with non-diamond coatings (e.g. nitrides, oxides, borides) typically exhibit flank wear. Tools with diamond coatings show the problem of coating flaking. PCD tools exhibit edge rounding. Results from testing also show that only the diamond based solutions such as the Chemical Vapour Deposition (CVD) diamond coatings and PCD could significantly reduce tool wear rate. The reduced wear rate is believed to be connected to the very high hardness of the diamond.
9:40 AM G4/E4-7 Fatigue Behavior of TiN Coating on WC-Co Cemented Carbides
Jun-Feng Su, Xueyuan Nie, Henry Hu (University of Windsor, Canada)
Titanium nitride (TiN) is used as a protective coating on cemented carbide cutting tools to improve tool life and superficial quality of the workpiece. However, TiN is relatively brittle and could fail due to fatigue cracking-induced wear under localized contact stresses during the milling operation in which the combined motion of impact and sliding displacement between cutting tools and chips from the workpiece. In the present work, the fatigue behavior of TiN coatings on WC-Co carbides was investigated using a novel impact-sliding wear tester, which simulates a reciprocal movement of combined impact and sliding motions. The TiN coatings on the surface and cross-section were studied using Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray (EDX) analysis. The degree and mechanism of the coating failure was evaluated by taking into consideration the properties of TiN coating and WC substrates. The test results provided constructive knowledge in selection and development of coatings for cutting tools.
10:00 AM G4/E4-8 Improved Cutting Processes of Austenitic Steels with γ-Alumina Based PVD Coating Systems
Susanne Cordes (RWTH Aachen University, Germany)

The machining of difficult-to-cut materials as austenitic steels is the focus of investigations for a long time now. One approach to overcome the problems when machining these materials is an appropiate coating system for the cutting tool. Especially the γ-phase of alumina is interesting for cutting operations due to its outstanding characteristics, such as high hot hardness, high thermal stability and low tendency to adhesion.

The deposition of alumina by using the Magnetron Sputter Ion Plating (MSIP)-PVD process faces different challenges: Deposition rates are low and insulating layers on the target surface can cause arcing. The development for deposition of oxides was first done by using radio frequency (r.f.) power supplies. This kind of process results in very low deposition rates, mostly amorphous structures of the coatings and expensive costs for ceramic targets and power supplies. During the last years, the deposition of oxides by the use of pulsed power supplies became more economically.

In the present work a (Ti,Al)N/γ-Al2O3-coating is deposited on cemented carbide in an industrial coating unit by means of MSIP. The (Ti,Al)N bond coat was employed to improve the adhesion of γ-Al2O3 on the substrate. The objective of this work is to study the wear mechanisms and the cutting performance of aluminium oxide based coated tools in turning, drilling and milling operations of austenitic steels, supplementary in combination with innovative environmental friendly lubricants. Based on the remarkable properties of this coating system the performance of the cutting tools is increasing significantly.

10:20 AM G4/E4-9 An Investigation into the Tribological Performance of PVD Coatings on High Thermal Conductivity Cu Alloy Substrates and the Effect of an Intermediate Electroless Ni-P Layer Prior to PVD Treatment
Junia Cristina Avelar-Batista Wilson (Tecvac Ltd, UK); Sarah Banfield (Tecvac Ltd and University of Sheffield, UK); John Eichler, Adrian Leyland, Allan Matthews (The University of Sheffield, UK); Jonathan Housden (Tecvac Ltd, UK)

The use of high thermal conductivity copper alloys in plastic injection moulds provides the benefit of rapid moulding cycles through effective heat transfer. However copper alloys are relatively soft and wear rapidly so manufacturers are developing new copper alloys with increased hardness and wear resistance. This wear resistance can be further improved by the deposition of hard coatings such as electroplated chromium, electroless Nickel and PVD coatings. In this paper, the tribological performance of three proprietary high-strength Cu alloys (Ampcoloy 940, Ampcoloy 944 and Ampcoloy 83) coated with PVD CrN and CrAlN coatings has been evaluated. A medium phosphorous content electroless Ni-P (ENi-P) plated layer was also deposited as a pre-treatment to PVD CrN and CrAlN coatings to increase the load support. The effect of this intermediate ENi-P layer was also evaluated. Surface roughness and ultra-microindentation hardness measurements were used to characterise all coated systems in both plated (i.e., with the intermediate ENi-P coating) and standard (i.e. unplated) conditions. Scratch tests were also performed to evaluate the effect of the ENi-P on PVD coating adhesion to Cu alloy substrates. The tribological behaviour of PVD-coated Cu alloy systems was evaluated by pin-on-disc wear tests and ball-on-plate impact tests. Results demonstrate that the ENi-P layer improves the load support for PVD coatings on Cu alloys, thereby improving their tribological performance. However, for PVD-coated Cu alloys in the standard condition, the Cu alloy substrate type plays an important role in the tribological performance of PVD coatings. For instance, PVD CrN coatings were more suited to a certain Cu alloy type whilst CrAlN to the other two types.

10:40 AM G4/E4-10 Mechanical Properties of Partially Oxidized Silicon Nitride Films Deposited by RF Reactive Magnetron Sputtering
Juline Filla, César Aguzzoli, Vânia Sonda, Cintia Amorim (Universidade de Caxias do Sul, Brazil); Gabriel Soares, Israel Baumvol (Universidade Federal do Rio Grande do Sul, Brazil); Carlos Figueroa (Universidade de Caxias do Sul, Brazil)
Hard coatings are widely used in surface engineering for wear protection and friction reduction of mechanical components. Nowadays, dry machining technologies are emerging techniques due to both reduction costs and environmental aspects. In fact, new coatings are being developed for high temperature applications, such as AlCrN, WC/C, Si3N4, as well as several multilayered coatings. However, the excellent performance, in terms of wear and corrosion resistance, of Si3N4 thin films in cutting tools at higher temperatures than 1000oC is still not fully understood.

In this work, silicon nitride thin films were deposited on Si(100) substrates by rf reactive magnetron sputtering from a Si target in a Ar/N2 plasma at variable substrate temperatures. In order to reproduce the oxidation conditions of cutting tools in dry machining, the samples were oxidized in 18O atmosphere at temperatures of 500 and 1000oC. Afterward, the thin films were characterized by glancing angle X-ray diffraction, X-ray reflectometry, Rutherford backscattering spectrometry, narrow nuclear resonant reaction profiling, nano-hardness and nano-scratch and friction measurements. Si3N4 stoichiometric films are obtained. Although the oxide layer thickness increases with temperature, silicon nitride thin films show a high corrosion resistance where the oxide layer thickness achieves a maximum value of 6-7 nm at an oxidation condition of 1 h and 1000oC. Nanohardness increases with deposition temperature as well as the compound density. Before oxidation, the friction coefficient follows a random behavior. After oxidation at both 500 and 1000oC temperatures, the friction coefficient follows a clear tendency where lower friction forces are measured when lower normal forces are applied. Such lower friction coefficients are attributed to a higher contribution of the oxide layer in the mechanical system. Finally, the thin oxide film obtained after dry machining at high temperature leads to improve the corrosion resistance and decrease the friction forces and, consequently and due to the maintenance of the hardness even at higher temperatures, the wear resistance is enhanced.

11:00 AM G4/E4-11 Carbon Based Coatings for Machining of Aluminum and Magnesium Alloys
Ahmet Alpas, Sukanta Bhowmick (University of Windsor, Canada); Michael. Lukitsch (General Motors Research and Development Center)
Carbon-based coatings, particularly diamond like carbon (DLC) coatings exhibit low coefficients of friction (COF) against aluminum and magnesium and allow minimal amount of material adhesion to their surfaces when tested under the ambient conditions. The favourable tribological properties of DLC coatings have generated interest in using them as tool coatings for machining of lightweight aluminum and magnesium alloys. This talk is organized in two parts; first the adhesion mitigating properties of non-hydrogenated DLC (NH-DLC) coatings tested under various environmental conditions will be presented, the role of atmospheric humidity on reducing the COF and the material transfer will be discussed by examining surface passivation and carbonaceous layer formation mechanisms at the interfaces. Then, the performance of DLC coated tools in drilling of commercial cast aluminum and magnesium alloys under minimum quantity water lubrication (H2O-MQL) condition will be considered. Experiments have shown that he H2O (30 ml/h) -MQL drilling of 319 Al alloys using NH-DLC coated tools has improved the tool life and reduced the drilling torques and thrust forces considerably compared to dry drilling of this alloy. The effect of NH-DLC coatings in drilling of and AZ91 Mg alloy was more dramatic as the drilling forces generated during H2O-MQL drilling were found to be as low as those measured during flooded drilling using conventional coolants. The improvements in machining using DLC coated tools will be discussed in terms of their tribological properties and microstructural changes that occur in the workpiece during machining.
Time Period WeM Sessions | Abstract Timeline | Topic G Sessions | Time Periods | Topics | ICMCTF2011 Schedule