ICMCTF2009 Session G7: Advances in Industrial PVD & CVD Deposition

Wednesday, April 29, 2009 1:30 PM in Room Royal Palm 1-3

Wednesday Afternoon

Time Period WeA Sessions | Abstract Timeline | Topic G Sessions | Time Periods | Topics | ICMCTF2009 Schedule

Start Invited? Item
1:30 PM G7-1 Innovative Applications Enabled by Large Area Hot Filament Diamond Deposition
J.W. Zimmer, D. Aidala, J Herlinger (sp3 Diamond Technologies)
Hot filament diamond coatings have traditionally been used only for cutting tool applications because of perceived limitations in film characteristics. Recently however improvements in the quality, range of morphology, and electrical characteristics of hot filament diamond have allowed many additional commercial applications to be addressed. This talk will discuss some of these new applications and how large area diamond deposition has enabled their growth.
1:50 PM G7-2 Industrial Scale Production of CVD-Diamond Coated Mechanical Seals and Electrodes
M. Rüffer, M. Foreta, J. Holzke, M. Nierada (DiaCCon GmbH, Germany); S. Rosiwall (University Erlangen Nürnberg, Germany)

The outstanding properties and advantages of crystalline CVD-diamond coatings applied onto high performance mechanical seals and electrodes are widely known. But similar to the diamond coating of tools an adopted coating set-up must be developed for industrial scale diamond coating of mechanical seals and electrodes. Mechanical seals ask for quite good flatness of sliding faces and electrodes require homogeneous, double side coating of large areas without bending or overheating of the metal substrate. For both applications different setups have been developed, by using the same platform, a CemeCon CC800/9.

For an economic industrial application a large filament array must be used to coat numerous or large parts in one batch. These filaments should perform long process times and must stand for several batch processes. Especially for coating of mechanical seals a horizontal setup assures the required flatness of the faces by providing homogeneous temperature distribution and gas composition over the complete coating area.

Since applications of diamond coated electrodes like waste water treatment usually need large coated areas and valuable substrate materials like Niobium, a double side coating of an electrode is preferred. The coating of such electrodes should be achieved in one batch without interrupting the process and turning the substrate. A vertical filament setup that is enclosing the electrode from both sides provides overall homogeneous distribution of doping elements (e.g. Boron), equal diamond quality and prevents bending at once.

We show that it is possible to coat with quite different setups different high performance products by using the same CVD-machine.

2:10 PM G7-3 Characterization of Industrial-Scale LAFAD Technology and Applications
V.I. Gorokhovsky (Arcomac Surface Engineering, LLC)
A unique industrial-scale Large Area Filtered Arc Deposition (LAFAD) process offers the opportunity for significant improvement in surface engineering technologies. The unidirectional LAFAD dual-arc vapor plasma source yields 100% ionized metal vapor plasma flow and more than 50% ionized gaseous plasma in the coating chamber. The dramatic increase of magnetized plasma propagating capabilities in LAFAD process produces substantially conformal coatings on complex shapes. The LAFAD technology deposits a thick ceramic and cermet coatings with multielemental nanostructured architectures, near defectless morphology and atomically smooth surface at high deposition rates. The operating range of LAFAD process allows it to combine with conventional EBPVD and magnetron sputtering in a hybrid surface engineering processes. The productivity of one unidirectional LAFAD vapor plasma source integrated in industrial scale batch coating system ranging from 3-4 µm/hr for nitride and carbide base coatings and up to 6 um/hr for oxiceramic coatings with required uniformity over large deposition areas, making it an attractive alternative to other PVD processes for wide variety of applications. The modular design of the LAFAD plasma source allows it to be easily integrated in any batch coating or in-line coating systems. The industrial applications of LAFAD process in deposition of wear and corrosion resistant coatings for forming tools and medical instruments, erosion resistant coatings for turbomachinery, tribological coatings on automotive and aerospace components, high temperature oxidation resistant coatings for SOFC and commercialization strategy of LAFAD technology will be discussed.
2:30 PM G7-4 Development of a Magnetically Steered Cathodic Arc Evaporation Source
K. Yamamoto, S. Tanifuji, S. Nakakubo, H. Fujii, Y. Kurokawa, S. Kujime (Kobe Steel Ltd., Japan)

Cathodic arc evaporation process (AIP) is nowadays well established and widely adopted in many industries involved with thin film technology, mostly for triboligical applications such as cutting tools. As already well recognized, arc plasma is characterized by high degree of ionization ratio up to 90 % which assures superior adhesion and densification of the coating. High deposition rate is also an advantage of the cathodic arc compared to sputtering or other industrial PVD process for hard coating. Most recognized drawback is emission of macro-particles (MPs) which is considered more or less unavoidable nature of the cathodic arc process. Kobe steel has been a pioneer in realization of magnetically steered arc technology for industrial use and in this paper, a novel cathodic arc evaporation source based on magnetic steering principle and coating properties are reported. A magnetically arc evaporation source based on a new magnetic field design was developed and deposition of various hard coating, such as TiN, (Ti,Al)N, (Al,Cr)N and (Ti,Cr,Al)N was conducted in a industrial coating system. Surface roughness of standard 3 µm (Ti,Al)N coating from our previous two kinds of arc source is Ra=0.2µm for random arc and Ra=0.1µm for plasma enhanced cathode1. Whereas the surface roughness can be as good as 0.02µm for 3 µm (Ti,Al)N coating deposited by the new arc source. Similar significant improvement in surface roughness can be observed for other major nitride coatings. The other characteristic of the coating deposited by the new source is significant reduction in residual stress. Residual stress of a few Gpa is commonly observed for arc deposited nitride coatings, whereas for the coatings deposited by the new source, the stress can be as small as 0.02GPa. A very thick (Ti,Al)N coating up to 20 µm can be grown on very sharp edge of a cutting tool without any chipping. Cutting test showed a significant enhancement in the tool life compared to a standard (Ti,Al)N coating with a few microns of thickness. Application of the new source to other coating systems will be reported.

1K. Yamamoto, T. Sato, K. Takahara, K. Hanaguri, Surface and Coatings Technology 174 –175 (2003) 620–626.

2:50 PM G7-7 Integration Aspects of High Impulse Magnetron Sputtering Plus (HIPIMS+) Technology in an Industrial PVD Coating Machine
F. Papa, R. Tietema, T. Krug, C. Strondl, I. Kolev (Hauzer Techno Coating BV, Netherlands)
Recent developments in the field of High Power Impulse Magnetron Sputtering (HIPIMS) have instigated great interest from both the academic and industrial worlds. The promise of ionized sputtered material creates the possibility for metal ion assisted deposition. This opens a new world of possibilities for creating defect free, conformal coatings with tailored microstructures. For academic research, small cathodes requiring low average powers are used. However, in order for HIPIMS technology to have commercially interest, it must be scaled up for large scale industrial PVD coaters. This requires a reliable power supply which can deliver an average power between 10 and 40kW. In addition to the HIPIMS supply itself, considerations must also be made for the design of different parts of the machine, such as the bias supply and magnetic field design of the cathode. HIPIMS+ is a platform which encompasses all aspects which are necessary for the industrial commercialization of HIPIMS technology. The properties of HIPIMS+ deposited coatings such as Titanium Nitride (TiN), Chromium Nitride (CrN) and Aluminum Titanium Nitride (AlTiN) will be presented. Potential tool and tribological applications will also be discussed.
3:10 PM G7-8 The New Vacotec/Eifeler Alpha 400/900P PVD Deposition System as a Basis for Innovative Coatings for Industries and Research
H. Hrubý, E. Voss, G. Keiren (Eifeler Werkzeuge GmbH, Germany); J. Anklam (Vacotec S.A., Switzerland)

The successful and innovative concept of Vacotec/Eifeler PVD technology based on the Alpha 400P coating system has been recently demonstrated1.

These new Alpha 400/900P arc coaters show a broad variety of technical features to produce state of the art PVD coatings for industrial as well as R&D applications.

Highlighted are the flexibility for hard and lubricant coatings as well as the combination of in-situ plasma-nitriding with a hard coating. With these standard features of the new generation machines it is easy to create well adopted PVD coatings which are nicely fitting for many special applications.

Using the DC arc with very high plasma density offers the ability to produce films of high density and superb wear resistance features. This will be demonstrated with nanostructured AlTiN-based films and their properties.

Regarding the operating costs it is shown that the concept of multiple arc sources is a ve ry competitive way to produce high quality wear resistant films for industrial use. And the concept offers the possibility to produce PVD films out of up to 4 different cathode materials at a very high deposition rate.

A couple of applications concerning metal cutting, metal forming and component coating will demonstrate the broad flexibility of the presented PVD machine concept. Limitations of the concept and technology and some ideas how to overcome these will be discussed.

1J. Anklam et al., ICMCTF 2008, G7-11.

3:30 PM E4/G4-9 Hot Filament Diamond CVD – Technology and Applications
W. Reichert, R. Cremer, O. Lemmer (CemeCon AG, Germany)
Hot filament CVD is a well-established technology for coating of tools and other three-dimensional components with microcrystalline and nanocrystalline diamond. CemeCons state-of-the-art CC800/9 Dia coating unit produces advanced quality diamond films. Due to its large 3-chamber recipient and the new and easy to use operating software this coating machine uniquely combines high quality, high flexibility and economical production capability. CVD diamond coated tools are used in a variety of applications. To obtain best results the carbide material, tool geometry, coating, and application need to be matched. High precision tools are needed for accurate machining of graphite electrodes. In this case the diameter of the coated tool is of greatest importance. When drilling CFRP parts (carbon fiber reinforced plastics) for aerospace applications sharp cutting edges and abrasion resistant coatings are significant for the overall cutting performance. Similar challenging require ments need to be met when routing printed circuit boards (PCBs) or processing aluminum, MMC and other composite materials. The presentation will show new developments in hot filament technology and cutting test results in different materials.
Time Period WeA Sessions | Abstract Timeline | Topic G Sessions | Time Periods | Topics | ICMCTF2009 Schedule