ICMCTF1998 Session H1: Advanced Metalization: Materials and Processes

Wednesday, April 29, 1998 8:30 AM in Sunrise Room

Wednesday Morning

Time Period WeM Sessions | Abstract Timeline | Topic H Sessions | Time Periods | Topics | ICMCTF1998 Schedule

Start Invited? Item
8:30 AM H1-1 Advanced CVD/PVD Fill Techniques for Al and Cu
R. Mosley (Applied Materials, Inc.)
9:10 AM H1-3 Studies of Grain Structure Evolution in Al Thin Films Using ADEPT (Atomistic Simulator of Deposition Processes in Three Dimensions)
H. Huang, T. Diaz de la Rubia (Lawrence Livermore National Laboratory); G. Gilmer (Bell Laboratories)
Grain structure evolution in Al thin films during deposition or annealing is studied using ADEPT (atomistic simulator of deposition processes in three dimensions). Atoms are allowed to occupy lattice sites only, but they are assigned orientations associated with the grains they belong to. Atoms near grains boundaries are assgned higher potential energies by reducing the bond energies to atoms in neighboring grains with different orientations. These atoms are also given higher diffusivities, as compared to those in the bulk. These grain boundary properties are chosen according to the results of molecular dynamics studies together with available experimental and ab initio calculation results. Grain boundary migration is represented by changing the orientations of atoms in the boundary between neighboring grain orientations. The nucleation and growth of Al grains during deposition on an amorphous substrate is predicted by ADEPT. Increases in the grain size at the thin film surface, and coarsening of grains under the thin film surface are both predicted during deposition and annealing.
9:30 AM H1-4 Texture and Surface Roughness of PRCVD Aluminum Films
D. Yang, R. Jonnalagadda, T.S. Cale (Arizona State University); J. Hillman, R.F. Foster (Materials Research Corporation)
Rough surface morphology is one of the problems with some CVD aluminum films. Higher temperatures during the early stages of the deposition increase the nucleation density and result in films with lower surface roughnesses [1]. Higher temperatures during the initial stages could also enhance the surface diffusion of Al adatoms, enabling them to form a higher fraction of (111) clusters. Al(111) textured films with narrow grain distributions are apparently the most resistant to electromigration [2]. Based on results from our earlier work [1] on temperature ramped process protocols during TIBA sourced programmed rate chemical vapor deposition (PRCVD) of aluminum, we designed experiments to investigate the effects of substrate type, carrier gas, and dilute gas flows on the film properties. Our results showed that pulsing the precursor flow on different substrates for 5 s at the start of temperature ramp down from 673 K followed by deposition for 25 s at 573 K resulted in films with higher nucleation densities and larger fractions of Al(111) texturing, in addition to lower surface roughnesses and smaller grain sizes. The fraction of (111) texturing was highest for the film deposited on TiN coated Si(111) substrates. For 10 min depositions using four different temperature protocols, the type of substrate significantly affected the fraction of Al(111) texturing and resistivities. During the temperature ramp down protocol, introduction of 100 sccm of dilute gas flow at 573 K reduced the grain size and root mean square (RMS) surface roughness. Initiating deposition at a lower carrier gas flow rate (30 sccm) at 673 K followed by deposition at the normal carrier gas flow (60 sccm) at 573 K, resulted in lower film grain size and root mean square (RMS) surface roughness. 1. D. Yang, R. Jonnalagadda, V. Mahadev, T. S. Cale, J. T. Hillman, R. F. Foster, and B. R. Rogers, Thin Solid Films (under publication) 2. Y. W. Kim, I. Petrov and J. E. Green, J. Vac. Sci. Technol. A 14(2), 346 (1996).
9:50 AM H1-5 A Low Temperature Integrated Aluminum Metallization Technology ULSI Devices
T. Guo, L.Y. Chen (Applied Materials, Inc.); D. Brown (Advanced Micro Devices); S. Voss, R. Mosely (Applied Materials, Inc.)

With ever increasing device density and shrinking feature dimensions, successful plug and interconnect metallization for 0.25 μm technology and beyond becomes very critical for the semiconductor industry. Utilizing advantages of CVD and PVD aluminum processes, we have successfully applied an integrated metallization scheme, the Cool Al process, to the back-end device fabrication for 0.25 μm technology. This integrated process allows low temperature aluminum metallization (< 360C), and is capable of reliably filling sub 0.25 μm structures.

The CVD aluminum and PVD aluminum deposition processes have been integrated on a Endura cluster metallization tool for the first time. A thin CVD aluminum film is first deposited on a nucleation film, typically Ti or Ti/TiN, using dimethyaluminum (DMAH) as precusor, at a process temperature of ~ 260C. Without vacuum break, a PVD aluminum deposition is carried out to complete the via fill. The contaminant-free, comformal thin CVD aluminum servers as an ideal wetting layer for the PVD aluminum planarization step, allowing enhanced diffusion of aluminum atoms to flow into vias at lower process temperature. In this work, we have used three different integration sequences to process the devices wafers with various nucleation films for CVD aluminum: (1) Coherent Ti; (2) Coherent Ti and CVD TiN; and (3) Coherent Ti, with an thin PVD aluminum film. Sequence (2) eliminates the TiAl3 formation in the vias, whereas sequence (3) results in better film texture. Excellent electro-migration performances were obtained on these devices, equal to or better than that of standard W technology. In addition, the via resistance for the three sequences will be presented and compared with the W technology. Lastly, the surface morphology and texture for the aluminum film characterized using AMF and SEM will be presented.

In summary, this single-pass aluminum plug and interconnect metallization process provides reliable via fill for 0.25 μm technology at low temperatures, with excellent electrical and reliability results. It also simplifies the manufacturing sequence, compared with other plug-fill technologies, therefore reducing the cost and increasing the overall production throughput.

10:30 AM H1-7 Advanced Metallization Using High Pressure Technology
D.C. Butler, P. Rich, K.E. Buchanan, M.F. Fayaz (Trikon Technologies, United Kingdom)

As dimensions shrink, packing densities rise and vertical integration continues, device manufacturers are seeking metallization solutions that combine low costs with high performance and reliability. In the fields of high performance microprocessors and DRAM's, new interconnect challenges are testing device designers and equipment vendors alike.

In the majority of DRAM's, stacked capacitor structures are used. The continuing drive to reduce cell size without losing storage capacity has increased the complexity and therefore the height of the capacitor structure. Consequently, as memory density rises, so does contact hole aspect ratio. In advanced DRAM manufacture, traditional metallization techniques will have difficulty maintaining yield as aspect ratio's rise above 6:1. Furthermore, the cost and density benefits of dual damascene processing are expected to be exploited by DRAM manufacturers, putting additional demands on the metallization scheme.

At and beyond the 0.25 μm node, interconnect delay replaces gate delay as the limit on microprocessor device performance. In response, 1997 saw a rapid acceleration in the development of low resistance copper interconnect schemes. In parallel, other workers have found significant speed benefits in combining Aluminium interconnect with low capacitance dielectrics. Dual damascene patterning techniques are also the subject of intense development in advanced logic lines.

This paper discusses the Forcefill process. This technology uses high pressure to assist fill of contact holes and vias. The paper will discuss the challenges of Aluminium plug processing and will present data from a novel in-situ process designed to extend hole-fill performance to very high aspect ratio structures. In addition, data will be given demonstrating the effectiveness of the process in dual damascene schemes. Finally, the paper will discuss the relevance of the Forcefill technique to the new materials and demands of the sub-0.25 μm era.

11:10 AM H1-9 Precipitation Processes in Al - 0.5% Cu Alloys
A.B. Cheney (The University of Alabama at Birmingham); J.H. Givens (Micron Technology, Inc.); J.M. Rigsbee (The University of Alabama at Birmingham)
Precipitation processes in Al-0.5 wt.%Cu thin films sputter deposited onto (001) Si wafers were investigated with transmission electron microscopy (TEM). Al-Cu films, with and without a Ti underlayer, were examined for Cu solute level and precipitate content in the solution-treated condition, followed by heat treatment at temperatures of 85 and 100C. Evolution of precipitate nucleation and growth was monitored as a function of aging time for time periods of up to 144 hours. Results showed that grain boundary triple points dominated as the preferred sites for precipitate nucleation and growth. Precipitate formation was accompanied by a detectable decrease in the copper solute level within the aluminum grains.
11:30 AM H1-10 Electro-Chemical Deposition Technology for ULSI Multilevel Copper Interconnects
C.H. Ting (CuTek Research Inc.); V.M. Dubin (AMD Corp.)
Copper is a promising candidate to replace aluminum ULSI metallization for better conductivity and reliability. The in-laid metal, or damascene, process has been developed to fabricate Cu conductors to give a planarized surface as well as avoiding the need for Cu etching. Although both PVD and CVD have been used to deposit gap filling copper but the best method turns out be electro-chemical deposition technology. Electrochemically deposited Cu, both electroless as well as electroplating, were used extensively in the fabrication of circuit boards but its use in ULSI interconnects has been relatively new (1, 2, 3). In addition to its superb gap filling capability, the electrochemical Cu deposition process also provides significant cost reduction over the PVD and CVD processes. The electrochemical Cu deposition techniques were used to fill 0.25 micron lines with depth up to one micron. The effective resistivity of electroplated in-laid Cu lines is below 2 micro-ohm-cm. The electrical uniformity of less than 1.5 % has been demonstrated with electroplated Cu films over 200 mm wafers. The impurity level for electroplated Cu films was measured in the ppm range. Furthermore, strong <111> texture, large grains and low stress Cu films were obtained with electroplating. Electrochemically deposited Cu together with Cu CMP were used to fabricate sub-half micron IC. Normal device and circuit characteristics were obtained. The process sequence as well as process integration issues will also be discussed. 1). P. L. Pai and C. H. Ting, Proc. of VLSI Multilevel Interconnection Conference, p. 258, 1989. 2). V. M. Dubin, Y. Shacham, B. Zhao, P.K. Vasudev and C. H. Ting, J. Electrochemical Soc., v. 144, p.898, 1997. 3). V. M. Dubin, C. H. Ting and R. Cheung, Proc. of VLSI Multilevel Interconnection Conference, p. 69, 1997.
Time Period WeM Sessions | Abstract Timeline | Topic H Sessions | Time Periods | Topics | ICMCTF1998 Schedule