AVS2015 Session 2D+EM+MC+MS+NS-MoA: 2D Materials: Devices and Applications

Avalanche photodiodes (APDs) are the semiconducting analogue of photomultiplier tubes offering very high internal current gain and fast response. APDs are interesting for a wide range of applications in communications, laser ranging, biological imaging, and medical imaging where they offer speed and sensitivity superior to those of classical p-n junction-based photodetectors. The APD principle of operation is based on photocurrent multiplication through impact ionization in reverse-biased p-n junctions. Here, we demonstrate APDs based on vertically stacked monolayer MoS₂ and p-Si, forming an abrupt p-n heterojunction. With this device, we demonstrate carrier multiplication exceeding 1000 at 10 V reverse bias . Our devices show little degradation of SNR at high gains. These heterostructures allow the realization of simple and inexpensive high-performance and low-noise photon counters based on transition metal dichalcogenides.

Phosphorus is one of the most abundant elements preserved in earth, constructing with a fraction of ~0.1% of the earth crust. In general, phosphorus has several allotropes. The two most commonly seen allotropes, white and red phosphorus, are widely used in explosives and safety matches. In addition, black phosphorus, though rarely mentioned, is a layered semiconductor and has great potentials in optical and electronic applications. Remarkably, this layered material can be reduced to one single atomic layer in the vertical direction owing to the van der Waals structure, known as phosphorene, where the physical properties can be tremendously different from its bulk counterpart. In this talk, we trace back to the 100 years research history on black phosphorus from the synthesis to material properties, and extend the topic from black phosphorus to phosphorene. The physical and transport properties are highlighted, aiming at further applications in electronic and optoelectronics devices.

Exfoliated black phosphorus (BP) is an elemental, two-dimensional (2D) nanomaterial with high carrier mobility (~100 cm²V^-1s^-1), a layer-dependent band gap (~0.3 to 2.0 eV), and in-plane anisotropy. Further, 2D BP is air sensitive, culminating in undesirable surface reactions that degrade device performance. We find that unencapsulated, exfoliated BP flakes form oxidized derivatives following ambient exposure, as ascertained by X-ray photoelectron spectroscopy, atomic force microscopy, Fourier transform infrared spectroscopy, transmission electron microscopy, and electrostatic force microscopy measurements. BP ambient oxidation is driven by oxygen-saturated H₂O, as we observe two-fold faster degradation for BP on hydrophobic substrates versus hydrophilic ones. After 48 hours of ambient oxidation, unencapsulated BP field-effect transistors (FETs) decline in mobility and current on/off ratio by factors of over 1000. In contrast, alumina (i.e., AlO_x) passivated BP flakes and FETs are robust and unoxidized for over seven months in ambient conditions. Alumina-passivated BP FETs possess mobilities of ~100 cm²V^-1s^-1, on/off ratios of 1000, and ambipolar transport, even following extensive ambient exposure [1]. This understanding of BP ambient oxidation—and how to prevent it—is also impacting ongoing work in solution-phase BP separation [2], BP chemical modification, and high-performance BP optoelectronic applications.

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[1] J. D. Wood et al., Nano Lett. 14, 6964 (2014); [2] J. Kang et al., ACS Nano 9, 3596 (2015).