AVS2015 Session SP+2D+AS+NS+SS-WeA: Probing Electronic and Transport Properties

Topological insulators (TI) with characteristic topological surface states (TSS) attract great interest for both fundamental physics and device applications. However, the unavoidable presence of defects in bulk single crystals usually dopes the material leading to a metallic behavior. Thus, the direct measurement of the TSS electronic transport properties is hard to achieve due to the dominant contribution from the bulk states. Here, we measure the transport properties of Bi₂Se₃ crystals by Four Probe Scanning Tunneling Microscopy (4P-STM) technique at different temperatures on fresh surfaces obtained by cleavage in Ultra-High Vacuum (UHV) (base pressure = 2x10^-10 Torr). In contrast to conventional models that assume two resistors in parallel to count for both the TSS and bulk conductance channels, we show that this technique can be used to differentiate the 2D contribution of TSS to the transport from the 3D contribution (bulk) by considering the potential profiles across the interface. Our method allows quantitative determination of conductivities from both channels. We also compare our results with samples exhibiting pure 2D and 3D transport behaviors. Our results shows that our approach enables direct distinguishing and accessing electronic transport of TI surfaces surface states, which can be applied to the studies of 2D to 3D crossover of conductance in other complex systems.

This research was conducted at the Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility.

Chiral edge states are one of the most fascinating hallmark of topological insulators [1-4]. While chiral edge states are the vitally important feature of 2D and 3D topological insulators, no correspondence has yet been found in 1D. On the other hand, in 1D, a Peierls-distorted atomic chain such as polyacetylene has two topologically different ground states and a topological edge state or so-called a topological soliton connecting between them [5,6]. The topological edge states in 1D show many interesting properties such as charge-spin separation, fractional charge, and so on [7,8]. However, they do not exhibit chirality as 2D or 3D topological insulators do. In this talk, we report that the 1D topological edge states, solitons, of the charge-density wave (CDW) system of indium atomic wires self-assembled on a silicon surface have the chiral property [9,10]. Our system can be well described by a coupled double Peierls-distorted atomic chain with zigzag interchain coupling, which induces dynamical sublattice symmetry breaking. This subtle change ensures a dynamically generated topological structure with four-fold symmetric ground states and has topological edge states with a new degree of freedom, chirality, which is absent in the case of a single Peierls atomic chain. We have performed scanning tunneling microscopy and spectroscopy in order to obtain experimental evidences of the chiral edge states in the 1D CDW. Individual right- and left-chiral edge states are directly identified from non-chiral ones, which are similar to the topological solitons found in a single Peierls atomic chain. Furthermore, we found that chiral edge states can produce quantized charge pumping across the chain that is topologically protected and controllable by their chirality. Thus, these topological chiral edge states or solitons can be utilized for future single-electron-level data storage devices or logic circuits, which are topologically protected.

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2. M. König, S. Wiedmann, C. Brüne, A. Roth, H. Buhmann, L. W. Molenkamp, X.-L. Qi, and S.-C. Zhang, Science 318, 766 (2007).
3. M. Z. Hasan, C. L. Kane, Rev. Mod. Phys. 82, 3045 (2010).
4. X.-L. Qi, S.-C. Zhang, Rev. Mod. Phys. 83, 1057 (2011).
5. W. P. Su, J. R. Schrieffer, A. J. Heeger, Phys. Rev. Lett. 42, 1698 (1979).
6. R. Jackiw, C. Rebbi, Phys. Rev. D 13, 3398 (1976).
7. T. Giamarchi, Quantum Physics in One Dimension (Oxford University Press, Oxford : New York, 2004).
8. T. Dauxois, M. Peyrard, Physics of Solitons (Cambridge University Press, 2006).
9. T.-H. Kim, H. W. Yeom, Phys. Rev. Lett. 109, 246802 (2012).
10. S. Cheon, T.-H. Kim, S.-H. Lee, H. W. Yeom, under review.

Two-dimensional (2D) hexagonal boron nitride (h-BN) monolayers have wide promising applications in nanoelectronics. The presence of defects could greatly impact its electronic properties. Here, we present experimental results about two types of line defects in h-BN monolayers, prepared on Cu foils by chemical vapor deposition (CVD) method.

Using scanning tunneling microscopy/spectroscopy (STM/STS), the structural and electronic properties of two types of quasi-1D defects are characterized in monolayer h-BN. An energy gap ~4 Ev is observed for h-BN monolayers on Cu foils. The first type of quasi-1D defects is the worm-like defects with length 3~30 nm, and width ~1.5 nm. Nano-ripples with modulation λ ~ 5.2 Å, which is about double the size of h-BN lattice, are observed both from the topographic images and Di/Dv mappings along the worm-like defects. The modulation is in phase at negative bias and out of phase at positive bias between the topographic images and Di/Dv mappings. The defects also show higher tunneling conductance than the h-BN sheet in the Di/Dv mappings. The observed nano-ripples in the defects might indicate interesting electronic properties, such as charge density wave (CDW).

The other type of defcts are the linear boundaries of h-BN. The tilting angle between the two domains at the both sides of the boundary is about 90°, which is well in line with our simulations. From the Di/Dv mapping, the boundary shows lower tunneling conductance than the h-BN sheet, which is different from the first type of quasi-1D defects.

Our experimental results demonstrate that the existence of quasi-1D defects tramendously affect the structure and electronic properties of h-BN, thus could be used to tune the transport properties in h-BN-based nanodevices.

This research was conducted at the Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility, and supported by the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the US DOE.

A single atomic spin constitutes the ultimate limit to the miniaturization of magnetic bits. Can the state of such a spin be made stable against the quantum mechanical tunneling of magnetization? The energy relaxation time, T1, of single spins on surfaces can be measured by spin-polarized pump-probe STM [1]. To date, the relaxation times reported for Fe-Cu dimers on Cu₂N insulating films have been of the order ~100 ns [1]. A three-order-of-magnitude enhancement of lifetime, to ~200 µs, was recently demonstrated for Co on a single-monolayer of MgO [2]. This was accomplished by choosing a less conductive decoupling layer to electronically separate the atom from a metal substrate, along with the careful design of the symmetry of orbital states. Here, we report on the tailoring of the T1 lifetime of single Fe atoms on single- and multi- layer MgO films grown on Ag(001). We focus on the characterization of intrinsic lifetimes for the atom-substrate system which are independent of the STM tip used to probe them, that is, without influence of the nearby STM tip which can be a strong source of electronic de-excitation. We also report on new advances in pump-probe techniques which were necessary to carry out these measurements. These advances extend lifetime detection to the femto-ampere and many-millisecond regimes demanded by the Fe on MgO system.

[1] Loth et al., Science 329, 1628 (2010)

[2] Rau et al., Science 344, 988 (2014).

The ability to create arbitrary stacking configurations of layered two-dimensional materials opens the way to the creation of designer band structures in these materials. Graphene on hexagonal boron nitride is an example of such a van der Waals heterostructure where the electronic properties of the composite material can be different from either individual material [1]. These van der Waals heterostructures can be formed using a wide variety of layered materials including from transition metal dichalcogenides, graphene and topological insulators. This talk will focus on devices consisting of graphene coupled to other layered materials. The lattice mismatch and twist angle between the layers produces a moiré pattern and affects their electronic properties. In double layer graphene systems, we find a van Hove singularity whose energy depends on the rotation angle [2]. This singularity in the density of states leads to a strong enhancement of the absorption at a particular wavelength. In graphene on transition metal dichalcogenides, the interaction between the materials leads to the possibility of commensurate stackings and the presence of new states in graphene [3].

[1] M. Yankowitz et al., Nature Physics 8, 382 (2012).

[2] S. Huang et al., arXiv:1504.08357 (2015).

[3] M. Yankowitz et al., Nano Letters 15, 1925 (2015).