Recently, 3-dimensional (3D) or 2-dimensional (2D) quantum dot superlattice are widely investigated to develop the new generation devices, such as quantum dot solar cell. Quantum dot superlattice consists of quantum dots with lower band gap energy in the matrix with higher band gap energy. For the device application, the structure requires high QD density, periodic QD array and uniform dot size and inter-dot spacing. Molecular beam epitaxy (MBE) and Metal-organic chemical vapor deposition (MOCVD) are two attractive methods among various bottom-up fabrication methods to fabricate quantum dots. However, there is limitation of bottom-up process to control the size, spacing and density of quantum dots. To brealkthrough these peoblems, we have proposed the ultimate top-down process by combination of bio-template and damage-free neutral beam etching (NBE) for fabricating defect-free 2D array of quantum dots.

In this study, we developed a series of novel process for fabricating uniform size and high density 2D array of GaAs nanodisk with unform inter-dot-spacing. Firstly, the hydrogen-radical treatment was used to remove the native oxide on GaAs surface. To utilize two-dimensional array of ferritin (protein including 7-nm-diameter iron core) as an etching mask, the formation of a hydrophilic 1-nm thick GaAs neutral beam oxidation film is key point. It is found that protein shell can be removed with oxygen-radical treatment at a low temperature of 280oC without thermal damage to GaAs. After protein shell removal, the iron oxide cores inside the ferritins remained on the surface. Then, using the iron core as an etching mask, neutral beam could etch the defect-free nanodisc structure of GaAs. Finally, we developed that iron oxide core was removed by wet etching with diluted hydrogen chloride and completed a fabrication process without inflicting any damage to GaAs. The result shows the quantum dot superlattice structure with a two-dimensional array of GaAs quantum dots with a diameter of ~7-nm, a height of ~10-nm, and a quantum dot density of more than 7×10¹¹cm^-2 was successfully demonstrated without any damage to GaAs.

For solar energy to be a significant component of our energy supply new technologies are needed that enable the fabrication of low cost, high efficiency solar cells. Research into solar energy devices which incorporate carbon fullerenes and semiconducting polymers represent one such technology. One factor limiting their further advance is their lack of absorption in the infrared (IR). As half the sun’s energy lies beyond 700 nm and one third beyond 1000 nm, low-cost device technologies are needed which capture this lost infrared potential. An additional factor limiting the further advance of these devices is the relatively poor electrical transport properties of most semiconducting polymers.

The use of solution processed quantum dots provides a potential route towards overcoming both of these limitations. Solution processed quantum dots can be tuned to absorb light well into the infrared, and quantum dot composite thin films have been shown to have charge carrier mobilities approaching that of amorphous silicon.

In this presentation we will present a brief overview of colloidal quantum dots and the field of quantum dot photovoltaics. We will discuss a range of device architectures and material systems that have been explored experimentally. This includes quantum dot-metal Schottky junctions, quantum dot heterojunctions, and quantum dot-metal oxide junctions.

Colloidal semiconductor nanocrystals (NCs) have attracted significant interest for applications in solution-processable devices such as light-emitting diodes and solar cells. However, poor understanding of charge transport in NC assemblies, specifically the relation between electrical conductance in dark and under light illumination, hinders their technological applicability. Here, we simultaneously address the issues of "dark" transport and photoconductivity in films of PbS NCs by incorporating them into optical field-effect transistors (OFETs), in which the channel conductance is controlled by both gate voltage and incident radiation. Spectrally resolved photoresponses of OFETs reveal a weakly conductive mid-gap band (MGB) which is responsible for charge transport in dark. The mechanism for conductance, however, changes under illumination when it becomes dominated by band-edge quantized states. In this case, the MGB still plays an important role as its occupancy (tuned by the gate voltage) controls the dynamics of band-edge charges. Our study has broad implications for NC-based electronics and optoelectronics, and specifically, suggests that design guidelines for NC devices might be different depending on whether they are intended for operation in dark (diodes and transistors) or under illumination (photodetectors and solar cells).

Small-diameter semiconductor nanowires are highly attractive building blocks for next generation photovoltaic devices because they exhibit highly tunable optoelectronic properties as a result of quantum confinement. Bottom up approaches, such as the vapor-liquid-solid (VLS) growth mechanism, are controllable down to ~20 nanometers but significant challenges exist at smaller length scales where property tuning is maximized. Furthermore, it is expected that the optoelectronic properties of quantum-confined nanowires will be heavily dependent on surface chemistry, yet there are no experimental studies that fundamentally probe this relationship. Germanium is an ideal system to study because of its large Bohr exciton radius, low rate of oxidation, and chemical similarity to silicon. In this work we controllably synthesize germanium nanowires with diameters from 5 to 20 nanometers using gold catalyst particles with a narrow size distribution. To obtain epitaxial Ge nanowires with uniform diameters and lengths, a two-step growth process is employed that includes a brief, high-temperature nucleation (390^oC) above the Au-Ge eutectic point, followed by elongation at various process conditions, generally below the eutectic point (280 – 340^oC, 1x10^-7 – 1x10^-4 Torr). To limit catalyst diffusion and formation of the √3 x √3 Au/Si reconstruction on the Si(111) surface, a key problem for controllable sub-20 nm growth, the substrate is passivated with -CH₃ groups prior to nanowire synthesis by introducing small quantities of methylgermane. Nanowire surface chemistry is probed with in-situ transmission infrared (IR) spectroscopy both during and after growth. We introduced different adsorbates (-H and -CH₃) and monitored their influence on the band gap as a function of surface coverage. We show that the band gap of Ge nanowires blue shifts with H passivation and red shifts with CH₃ termination.

Thermolysis of Zn and Cd precursors under a non-coordinating one-pot wet-chemical synthesis has successfully produced a heterogeneous ternary Cd_xZn_1-xSe alloy with an extensive spectral red shift of 200nm in the visible range. Large yields of twenty milligram of the Cd_xZn_1-xSe alloy are minimally required for inclusion of the material in the active layer of an inorganic/organic photovoltaic device. The facile synthesis of such large yields of ternary semiconductor nanocrystal alloys has not commonly been reported in the literature. Herein we discuss first the thermolytic synthesis of the material beginning from the ZnSe core through the inclusion of the Cd-precursor. We then discuss the production of the ternary II-VI semiconductor Cd_xZn_1-xSe material through a process of non-coordinating synthesis with amine-activation to produce the high multi-milligram yields required for device inclusion.