Given the strong interest in III-nitride-based nanowires for optoelectronic and energy applications, a better understanding of their optical properties and structure-composition is required, particularly at nanoscale spatial resolutions, which could shed light into issues such as the nature and distribution of radiative defects and alloy compositional variations. Here, we present a spatially-resolved, correlated study of luminescence and composition in GaN, Al(Ga)N/GaN, and InGaN/GaN core-shell nanowires grown by metal-organic chemical vapor deposition. For GaN nanowires, a surface layer exhibiting strong yellow luminescence (YL) near 566 nm in the nanowires was directly revealed by high resolution, cross-sectional cathodoluminescence (CL) imaging, compared to weak YL in the bulk. In contrast, other defect related luminescence near 428 nm (blue luminescence) and 734 nm (red luminescence), in addition to band-edge luminescence (BEL) at 366 nm, were observed in the bulk of the GaN nanowires but were largely absent at the surface. As the nanowire width approaches a critical dimension, the surface YL layer completely quenches the BEL. The surface YL is attributed to the diffusion and piling up of mobile point defects, likely isolated gallium vacancies, at the surface during growth. AlGaN/GaN and AlN/GaN core-shell nanowires were observed to exhibit stronger BEL and weaker YL as compared with bare GaN nanowires, which may relate to the passivation of nanowire surface states. InGaN/GaN core-shell nanowires were also investigated by correlated CL and cross-sectional scanning TEM (STEM). Dislocation-free InGaN layers with up to ~40% indium incorporation were achieved on GaN nanowires. The indium composition distribution in the InGaN layers were qualitatively correlated to the strain energy density distribution as calculated by finite element analysis models. The observed high indium incorporation and high crystalline quality in the heteroepitaxial InGaN layers is attributed to strain-relaxed growth on the nanowires. Sandia National Laboratories is a multi-program laboratory operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin company, for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-AC04-94AL85000.

For many years researchers have attempted to efficiently harvest waste heat and transform it into a usable energy via thermophotovoltics (TPVs). The low quantum efficiency (QE; i.e. the probability that a photon will be absorbed) in most TPV cells is probably the biggest limiting factor in achieving an economically viable device and directly affects the conversion efficiency (CE; i.e. the probability that a photon will be converted into a carrier that is collected). In many cases, top of the line TPV cells might only have a CE of 20%. Recent advances in micro-/nano-fabrication techniques have enabled the creation of novel structures to enhance the absorption and, therefore, the conversion of the incident thermal photons. In particular, photonic crystals (PhC) interface enhancements have been shown to increase the efficiency of photon to current conversions for infrared photodetectors. The addiction of a back reflecting layer, or vertical confinement layer can further increase conversion efficiencies. Here, we report on the enhancement of photon conversion by integration of PhC structures and vertical confinement layers into the TPV cells. To this end, photonic crystals consisting of rods of either air or dielectric surface-passivation material are placed into the base semiconductor TPV cells to increase duration of thermal photon absorption, resulting in significantly enhanced QE and CE. The use of photonic crystals and vertical confinement in augmenting the conversion efficiency of TPV cells is applicable for most IR wavelengths, making this a widely useful technology. The ability to harvest waste heat for energy will help make many processes and/or systems more energy efficient, which will be a critical component in ushering in an era of energy independence.

Recently we demonstrate plasmon-induced electronic transport in hybrid metal nanoparticle-molecular devices that realized enhancements of up to a factor of 200. This was realized in a hybrid structure that consists of an array of gold nanoparticles linked by (porphinato)zinc(II) oligomers. Here we examine the role of metal particle size, spacing, molecular length and radiation power on the photoconductive properties. Controlling these parameters allows the relative roles of nano antennae focus increasing effective photon flux and hot electron distribution to the current enhancement to be compared.

This phenomenon offers a pathway to selectively enhance specific optical energies or to design a hybrid structure that can simultaneously enhance a range of optical wavelengths. Applications in optical devices and a range of photovoltaics could exploit this new phenomenon [ACS Nano, 2010, 4 (2), pp 1019-1025] .

The combination of (noble) metal nanoparticles (NPs) with dielectrics is an on-going research subject, due to the generated surface plasmon reasonance (SPR) effect, relevant in several technological applications such as color filters, optical switching devices and sensors, to name a few.

In this contribution, we report on the tunability and control of the surface plasmon resonance behaviour through the engineering of metal NP/dielectric interfaces for two applications, i.e. thickness- and viewing angle- independent red- coloured decorative coatings and light trapping enhancement in silicon- based tandem thin film solar cells. Both studies have been carried out by making use of a vacuum chamber where plasma- enhanced chemical vapour deposition for the dielectric layer and magnetron sputtering for the metal NP deposition are combined.

Multilayer structures composed of gold NPs sandwiched between SiO₂ layers represent a valid solution for the independent control of NP size and density: while a constant NP size guarantees a narrow surface plasmon frequency, an increased NP density leads to an enhancement in the absorption [1]. A multi-diagnostic approach consisting of spectroscopic ellipsometry, transmission electron microscopy and Rutherford backscattering analysis has allowed the characterization of the deposited coatings: gold NPs (diameter 10-15 nm) with a surface area coverage of 26% and sandwiched between 40 nm- thick SiO₂ layers, exhibit a red colour, whereas the color intensity (i.e. from cool to warm deep red) increases with the layer number, i.e. NP density.

While in this first application the main mechanism contributing to extinction is absorption, for an efficient sun light management/ trapping within a solar cell, scattering plays a dominant role. In particular, for amorphous (a-Si:H)/microcrystalline (μc-Si:H) silicon tandem solar cells a promising approach consists in the incorporation of an intermediate layer (e.g. ZnO) sandwiched between the top a-Si:H and the bottom μc-Si:H cell, able to efficiently scatter photons of a specific frequency range back to the top cell or forward to the bottom cell. In this respect, copper NPs (30-150 nm diameter) when coupled to ZnO layers, are responsible for the generation of a plasmon peak at 700 nm, which shifts towards higher wavelengths with an increase in NP size, therefore showing its potential towards low energy photon forward scattering into the bottom μc-Si:H cell.

[1] H. T. Beyene, F.D. Tichelaar, P. Peeters, I. Kolev, M.C.M. van de Sanden, M. Creatore, accepted for publication in Plasma Processes and Polymers (2010).

Silicon nanowires (SiNW) show high potential as future building blocks for photonic devices. They show strong resonant enhancement effects resulting in high absorption efficiencies and even higher scattering efficiencies. Since both effects are based on the same underlying physical principles the resonant enhancement of the absorption as well the resonant enhancement of the scattering of light occurs at the same wavelength. These large scattering efficiencies could result in an increased reflectivity of structures based on these SiNWs.

To overcome the increased scattering efficiencies we show an index matching core-shell approach.

The SiNWs are wrapped with a thin oxide layer with a refractive index smaller than the refractive index of silicon. The thickness of the wrapping layer is formed using atomic layer deposition (ALD), which allows to control the thickness of the layer at the Angstrom scale. The microstructure is analyzed using transmission electron microscopy (TEM).

The scattering behavior of these individual SiNWs with an oxide layer are measured using an optical microscope with a coupled spectrometer. The experimental data is analyzed using an extended Mie theory.

It will be shown, that this method can be used to tune the absorption efficiencies and the scattering separately to different wavelengths.

We demonstrate efficient electrophosphorescence from devices comprised of a single organic active layer. High efficiency is realized by combining both hole- and electron-transporting host materials (HTM and ETM, respectively) into a single, graded composition emissive layer with the green emitter, fac-tris(2-phenylpyridine) iridium (III). The composition of the host-material is continuously graded to realize 100% HTM at the anode, and 100% ETM at the cathode. A peak external quantum efficiency of η_EQE=(19.3 ± 0.4) % is realized in the forward-viewing direction at a luminance level of 600 cd/m², corresponding to a power efficiency of η_P =(66.5 ± 1.3) lm/W. This performance is similar to that realized in more conventional and complex, multi-layered structures. The graded composition of the structure balances electron and hole injection and transport leading to efficient exciton formation, permitting high efficiency using a single active layer. The graded composition architecture may be further utilized to realize simple, efficient organic light-emitting devices for use in display and lighting applications.